Necklace‐like Nitrogen‐Doped Tubular Carbon 3D Frameworks for Electrochemical Energy Storage. (20th January 2020)

• Record Type: Journal Article
• Authors: Yuksel, Recep; Buyukcakir, Onur; Panda, Pritam Kumar; Lee, Sun Hwa; Jiang, Yi; Singh, Deobrat; Hansen, Sandra; Adelung, Rainer; Mishra, Yogendra Kumar; Ahuja, Rajeev; Ruoff, Rodney S.
• Is Part Of: Advanced functional materials. Volume 30:Number 10(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-01-20
• Subjects: energy storage -- metal–organic frameworks -- supercapacitors -- tetrapods -- zinc‐ion capacitors; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201909725
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: The design and synthesis of a necklace‐like nitrogen‐doped tubular carbon (NTC) are presented by growing microporous polyhedral ZIF‐8 particles and a uniform layer of ZIF‐8 on sacrificial ZnO tetrapods (ZTPs). Oxygen vacancies together with defect regions on the surface of the ZTPs result in the formation of ZIF‐8 polyhedra in conjunction with a very thin shell. This necklace‐like NTC structure has a high N content, very large surface area, ultrahigh microporosity, and quite high electrical conductivity. NTC‐based symmetrical supercapacitor and zinc‐ion capacitor (ZIC) devices are fabricated and their electrochemical performance is measured. The NTC supercapacitor shows an ultrahigh rate capability (up to 2000 mV s −1 ) and promising cycle life, retaining 91.5% of its initial performance after 50 000 galvanostatic charge–discharge cycles. An aqueous ZIC, constructed using the NTC, has a specific capacitance of 341.2 F g −1 at a current density of 0.1 A g −1 and an energy density of 189.6 Wh kg −1 with a 2.0‐V voltage window, respectively. The outstanding performance is attributed to the NTC high N‐doping content, a continuous "polyhedral 3D hollow" architecture and the highly porous microtubular arms exhibiting very high surface area. Abstract : A necklace‐like nitrogen‐doped tubular carbon (NTC) with a continuous polyhedral 3D hollow architecture and highly porous microtubular arms is fabricated by growing ZIF‐8 on sacrificial ZnO tetrapods (ZTPs). The symmetrical supercapacitor and zinc‐ion capacitor devices demonstrate that the NTC electrodes with univalent and multivalent electrolyte ions can be easily utilized for various aqueous‐based devices with high electrochemical performance.