Enantioselective Iodine(I/III) Catalysis in Organic Synthesis. Issue 1 (30th October 2018)
- Record Type:
- Journal Article
- Title:
- Enantioselective Iodine(I/III) Catalysis in Organic Synthesis. Issue 1 (30th October 2018)
- Main Title:
- Enantioselective Iodine(I/III) Catalysis in Organic Synthesis
- Authors:
- Flores, Andrea
Cots, Eric
Bergès, Julien
Muñiz, Kilian - Abstract:
- Abstract: Chiral aryliodine(III) reagents have provided an advanced concept for enantioselective synthesis and catalysis. With the advent of chiral iodine(I/III) catalysis, many different structures have been explored in the area. The currently most prominent catalyst design is based on a resorcinol core and the attachment of two lactic side chains bearing ester or amide groups. This enables a privileged modular catalyst synthesis, in which fine‐tuning with respect to the specific reaction requirement is straightforward. The present overview summarizes the structural variation and optimization of such chiral aryliodine catalysts and discusses structural properties of the active iodine(III) catalyst states. The status quo of enantioselective iodine(I/III) oxidation catalysis with respect to intramolecular and intermolecular reaction control is reviewed, and specific aspects of the individual catalytic cycles are discussed. Abstract :
- Is Part Of:
- Advanced synthesis & catalysis. Volume 361:Issue 1(2019)
- Journal:
- Advanced synthesis & catalysis
- Issue:
- Volume 361:Issue 1(2019)
- Issue Display:
- Volume 361, Issue 1 (2019)
- Year:
- 2019
- Volume:
- 361
- Issue:
- 1
- Issue Sort Value:
- 2019-0361-0001-0000
- Page Start:
- 2
- Page End:
- 25
- Publication Date:
- 2018-10-30
- Subjects:
- chirality -- enantioselective synthesis -- homogeneous catalysis -- iodine -- oxidation
Catalysis -- Periodicals
Organic compounds -- Synthesis -- Periodicals
Chemistry -- Periodicals
Chemistry, Technical -- Periodicals
Chemistry -- Periodicals
Catalysis -- Periodicals
Technology, Pharmaceutical -- Periodicals
547.2 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1615-4169 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/adsc.201800521 ↗
- Languages:
- English
- ISSNs:
- 1615-4150
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0696.931980
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 17475.xml