Nitriding‐Interface‐Regulated Lithium Plating Enables Flame‐Retardant Electrolytes for High‐Voltage Lithium Metal Batteries. (6th May 2019)

• Record Type: Journal Article
• Authors: Tan, Shuang‐Jie; Yue, Junpei; Hu, Xin‐Cheng; Shen, Zhen‐Zhen; Wang, Wen‐Peng; Li, Jin‐Yi; Zuo, Tong‐Tong; Duan, Hui; Xiao, Yao; Yin, Ya‐Xia; Wen, Rui; Guo, Yu‐Guo
• Is Part Of: Angewandte Chemie. Volume 131:Number 23(2019)
• Page Start: 7884
• Page End: 7889
• Publication Date: 2019-05-06
• Subjects: Batterien -- Grenzflächen -- Lithiummetallanoden -- Flammhemmende Elektrolyte; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201903466
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Safety concerns are impeding the applications of lithium metal batteries. Flame‐retardant electrolytes, such as organic phosphates electrolytes (OPEs), could intrinsically eliminate fire hazards and improve battery safety. However, OPEs show poor compatibility with Li metal though the exact reason has yet to be identified. Here, the lithium plating process in OPEs and Li/OPEs interface chemistry were investigated through ex situ and in situ techniques, and the cause for this incompatibility was revealed to be the highly resistive and inhomogeneous interfaces. Further, a nitriding interface strategy was proposed to ameliorate this issue and a Li metal anode with an improved Li cycling stability (300 h) and dendrite‐free morphology is achieved. Meanwhile, the full batteries coupled with nickel‐rich cathodes, such as LiNi0.8 Co0.1 Mn0.1 O2, show excellent cycling stability and outstanding safety (passed the nail penetration test). This successful nitriding‐interface strategy paves a new way to handle the incompatibility between electrode and electrolyte. Abstract : Eine nitrierende Grenzflächenschicht wurde entwickelt, die den erfolgreichen Einsatz von flammhemmenden Elektrolyten in Zellen mit Li‐Metallanode und Hochspannungs‐Hochleistungskathode ermöglicht. Die Homogenität der Festelektrolyt‐Grenzflächenschicht (SEI) ist entscheidend für die gleichmäßige Li‐Abscheidung, die für Hochspannungsbatterien benötigt wird.