Understanding polyoxometalates as water oxidation catalysts through iron vs. cobalt reactivity. Issue 25 (27th May 2021)

• Record Type: Journal Article
• Authors: Azmani, Khalid; Besora, Maria; Soriano-López, Joaquín; Landolsi, Meriem; Teillout, Anne-Lucie; de Oliveira, Pedro; Mbomekallé, Israël-Martyr; Poblet, Josep M.; Galán-Mascarós, José-Ramón
• Is Part Of: Chemical science. Volume 12:Issue 25(2021)
• Page Start: 8755
• Page End: 8766
• Publication Date: 2021-05-27
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/d1sc01016f
• Languages: English
• ISSNs: 2041-6520

Abstract

Abstract : This study explores the water oxidation catalytic activity of Fe-containing polyoxometalates. Comparative analyses with Co analogs identify the major descriptors for water oxidation catalysts based on robust and inexpensive materials. Abstract : Cobalt polyoxometalates (Co-POMs) have emerged as promising water oxidation catalysts (WOCs), with the added advantage of their molecular nature despite being metal oxide fragments. In comparison with metal oxides, that do not offer well-defined active surfaces, POMs have a controlled, discrete structure that allows for precise correlations between experiment and computational analyses. Thus, beyond highly active WOCs, POMs are also model systems to gain deeper mechanistic understanding on the oxygen evolution reaction (OER). The tetracobalt Weakley sandwich [CoII4(H2 O)2 (B-α-PW9 O34 )2 ] 10− (Co4 -WS ) has been one of the most extensively studied. We have compared its activity with that of the iron analog [FeIII4(H2 O)2 (B-α-PW9 O34 )2 ] 6− (Fe4 -WS ) looking for the electronic effects determining their activity. Furthermore, the effect of POM nuclearity was also investigated by comparison with the iron- and cobalt-monosubstituted Keggin clusters. Electrocatalytic experiments employing solid state electrodes containing the POMs and the corresponding computational calculations demonstrate that Co II -POMs display better WOC activity than the Fe III derivatives. Moreover, the activity of POMs is less influenced by their nuclearity, thus Weakley sandwich moieties show slightly improved WOC characteristics than Keggin clusters. In good agreement with the experimental data, computational methods, including p K a values, confirm that the resting state for Fe-POMs in neutral media corresponds to the S1 (Fe III –OH) species. Overall, the proposed reaction mechanism for Fe4 -WS is analogous to that found for Co4 -WS, despite their electronic differences. The potential limiting step is a proton-coupled electron transfer event yielding the active S2 (Fe IV O) species, which receives a water nucleophilic attack to form the O–O bond. The latter has activation energies slightly higher than those computed for the Co-POMs, in good agreement with experimental observations. These results provide new insights for the accurate understanding of the structure–reactivity relationships of polyoxometalates in particular, and or metal oxides in general, which are of utmost importance for the development of new bottom-up synthetic approaches to design efficient, robust and non-expensive earth-abundant water oxidation catalysts.