Deposition of hydroxyapatite coatings by axial plasma spraying: Influence of feedstock characteristics on coating microstructure, phase content and mechanical properties. Issue 8 (July 2021)

• Record Type: Journal Article
• Authors: Ganvir, Ashish; Nagar, Sainyam; Markocsan, Nicolaie; Balani, Kantesh
• Is Part Of: Journal of the European Ceramic Society. Volume 41:Issue 8(2021)
• Page Start: 4637
• Page End: 4649
• Publication Date: 2021-07
• Subjects: Axial plasma spraying -- Suspensions -- Phase degradation -- Hydroxyapatite coatings -- Microstructure -- Adhesion strength; Ceramic materials -- Periodicals; Composite materials -- Periodicals; Matériaux céramiques -- Périodiques; Composites -- Périodiques; Ceramic materials; Composite materials; Periodicals; Electronic journals; 666.05
• DOI: 10.1016/j.jeurceramsoc.2021.02.050
• Languages: English
• ISSNs: 0955-2219

Abstract

Graphical abstract: Highlights: An experimental study describing processing and phase degradation of hydroxyapatite (HAp) coatings during axial plasma spray. Studied the influence of feedstock (suspension as well as powder) characteristics on coating microstructure & phases. Discussed the in-flight particle treatment and subsequent phase degradation while injecting suspension and powder feedstock. Investigated the interplay between microstructure, phases, and coatings hardness as well as adhesion strength. Demonstrated the deposition of thin and adherent HAp coatings by axial suspension plasma spray with limited phase degradation. Abstract: Axial plasma spray is one of the thermal spray techniques to deposit multifunctional advanced coatings. The present work explores the use of this process to deposit thin, continuous, and adherent Ca5 (PO4 )3 OH (hydroxyapatite, HAp) coatings and characterize its microstructure, phases, hardness and adhesion strength. Three different suspension-deposited HAp coatings were investigated and compared with powder-deposited HAp coating on a Ti6Al4V substrate. The effect of mean solute particle size and solid-loading in the suspension has been explored on the evolution of microstructure, phase content and mechanical properties of axial suspension plasma sprayed (ASPS) coatings. Phase-characterization has shown retention of hydroxyapatite phase and coating crystallinity in the deposited coatings, whereas the adhesion strength of the HAp coating decreased from ∼40 MPa to ∼13 MPa when bioglass was added to the feedstock material. The lower solid load content and lower mean solute particle size in the suspension were found to be beneficial in achieving porous, rougher, and well-adhering coatings. This work concludes that ASPS can potentially deposit thin HAp coatings (< 50 μm) with high adhesion strength.