Detection and quantification of defect evolution at buried metal-oxide-polymer interface on rough substrate by local electrochemical impedance mapping. (20th August 2021)

• Record Type: Journal Article
• Authors: Sanchez, Thomas; Kurchavova, Ekaterina; Shkirskiy, Viacheslav; Światowska, Jolanta; Vivier, Vincent; Volovitch, Polina
• Is Part Of: Electrochimica acta. Volume 388(2021)
• Publication Date: 2021-08-20
• Subjects: Local electrochemical impedance spectroscopy -- Conversion coating -- Buried interfaces -- Material degradation; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2021.138467
• Languages: English
• ISSNs: 0013-4686

Abstract

Highlights: Controlled local oxide thinning on rough (Ra = 5 µm) substrate prior to painting. Oxide thinning on areas < mm 2 did not affect the electrochemical response. Nanometric oxide thinning on areas of ~ mm 2 and more affected underpaint stability. Reactivity front advancement from underpaint defect was quantified in situ by LEIM. LEIM discriminated degradation modes confirmed ex situ by optical microscopy. Abstract: The role of local nanometric thinning in trivalent chromium conversion coating for the electrochemical stability of buried metal-oxide-model epoxy interface formed on a rough (arithmetic average roughness parameter Ra = 5 µm) electrodeposited substrate is presented. For different morphologies and sizes of thinned zones, the buried interface stability was tested in AC-DC-AC procedure. Local oxide thinning at zones of <0.25 mm 2 was successfully detected by local electrochemical impedance mapping (LEIM). LEIM was able to measure in situ the interface degradation kinetics and distinguish the defects for which the interface underwent severe degradation from others in both terms of defect size and underpaint reactivity. The evolution of LEIM maps was in good agreement with the optical observations from 3D image reconstruction performed ex situ, thus validating quantitative LEIM as a tool for the local degradation quantification of buried interfaces. Based on the evolution of cathodic charge, LEIM and ex situ optical microscopy, it was demonstrated that the zone with local thinning of conversion coating on the rough substrates needs to reach some critical size to affect significantly the underpaint reactivity. Otherwise, the surface inhomogeneity related to the initial roughness hinders the effect of the local oxide thinning. Graphical Abstract: Image, graphical abstract