An alginate-confined peroxygenase-CLEA for styrene epoxidation. Issue 47 (14th May 2021)
- Record Type:
- Journal Article
- Title:
- An alginate-confined peroxygenase-CLEA for styrene epoxidation. Issue 47 (14th May 2021)
- Main Title:
- An alginate-confined peroxygenase-CLEA for styrene epoxidation
- Authors:
- Nintzel, Friederike E. H.
Wu, Yinqi
Planchestainer, Matteo
Held, Martin
Alcalde, Miguel
Hollmann, Frank - Abstract:
- Abstract : An alginate-confined peroxygenase-CLEA has been prepared for the stereoselective epoxidation of cis -β-methylstyrene under non-aqueous reaction conditions. Product titres of up to 48 mM and excellent enzyme turnovers of 96 000 have been achieved. Abstract : Oxyfunctionalisation reactions in neat substrate still pose a challenge for biocatalysis. Here, we report an alginate-confined peroxygenase-CLEA to catalyse the enantioselective epoxidation of cis -β-methylstyrene in a solvent-free reaction system achieving turnover numbers of 96 000 for the biocatalyst and epoxide concentrations of 48 mM.
- Is Part Of:
- Chemical communications. Volume 57:Issue 47(2021)
- Journal:
- Chemical communications
- Issue:
- Volume 57:Issue 47(2021)
- Issue Display:
- Volume 57, Issue 47 (2021)
- Year:
- 2021
- Volume:
- 57
- Issue:
- 47
- Issue Sort Value:
- 2021-0057-0047-0000
- Page Start:
- 5766
- Page End:
- 5769
- Publication Date:
- 2021-05-14
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d1cc01868j ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 17234.xml