Vapour–liquid equilibria in the system methanethiol–water. (September 2021)

• Record Type: Journal Article
• Authors: Jou, F.-Y.; Mather, A.E.; Schubert, C.N.; Schmidt, K.A.G.
• Is Part Of: Journal of chemical thermodynamics. Volume 160(2021)
• Publication Date: 2021-09
• Subjects: Methyl mercaptan -- Vapour–liquid equilibria -- Equation of state -- Henry's law constant; Thermodynamics -- Periodicals; Thermochemistry -- Periodicals; Thermodynamique -- Périodiques; Thermochimie -- Périodiques; Thermochemistry; Thermodynamics; Periodicals; 541.369
• DOI: 10.1016/j.jct.2021.106480
• Languages: English
• ISSNs: 0021-9614

Abstract

Highlights: The solubility of methanethiol in water was measured. The data were correlated with the Peng-Robinson equation of state. Henry's law constants were correlated with temperature. Abstract: The solubility of methanethiol in water was measured at temperatures in the range (298–413) K at pressures up to 1.1 MPa. The literature and the new data were correlated with the Peng-Robinson equation of state. Henry's law constants, from the literature and from the Peng-Robinson equation of state were correlated with temperature over a temperature range of 273.15 K–588.7 K.