A novel method to obtain integral parameters of the orientation distribution function of textured polycrystals from wavelength‐resolved neutron transmission spectra. Issue 3 (28th May 2021)

• Record Type: Journal Article
• Authors: Vicente Alvarez, Miguel Angel; Laliena, Victor; Malamud, Florencia; Campo, Javier; Santisteban, Javier
• Is Part Of: Journal of applied crystallography. Volume 54:Issue 3(2021)
• Page Start: 903
• Page End: 913
• Publication Date: 2021-05-28
• Subjects: wavelength‐resolved neutron transmission -- Bragg edge -- crystallographic texture -- material properties; Crystallography -- Periodicals; 548.05
• DOI: 10.1107/S1600576721003861
• Languages: English
• ISSNs: 0021-8898

Abstract

Abstract : The position and shape of Bragg edges in wavelength‐resolved neutron transmission spectra depend on the crystal structure and on the crystallographic texture of the material. This work describes a novel method to obtain integral parameters of the orientation distribution function from these spectra with the aim of estimating material properties. Abstract : A novel method to estimate integral parameters of the orientation distribution function (ODF) in textured polycrystals from the wavelength‐resolved neutron transmission is presented. It is based on the expression of the total coherent elastic cross section as a function of the Fourier coefficients of the ODF. This method is broken down in detail for obtaining Kearns factors in hexagonal crystals, and other material properties that depend on the average of second‐ and fourth‐rank tensors. The robustness of the method against three situations was analyzed: effects of sample misalignment, of cutoff value l max of the series expansion and of experimental standard deviation. While sample misalignment is shown not to be critical for the determination of Kearns factors and second‐order‐rank properties, it can be critical for fourth‐rank and higher‐order tensor properties. The effect of the cutoff value on the method robustness is correlated to the standard deviation of the experimental data. In order to achieve a good estimation of the Fourier coefficients, it is recommended that the experimental standard deviation be around 3–5% of the total scattering cross section of the material for the method to be stable. The method was applied for the determination of Kearns factors from transmission measurements performed at the instrument ENGIN‐X (ISIS) on a Zr–2.5 Nb pressure tube along two sample directions and was shown to be able to estimate Kearns factors with an error below 5%.