Utmost limits of various solid electrolytes in all-solid-state lithium batteries: A critical review. (July 2019)

• Record Type: Journal Article
• Authors: Wu, Zhijun; Xie, Zhengkun; Yoshida, Akihiro; Wang, Zhongde; Hao, Xiaogang; Abudula, Abuliti; Guan, Guoqing
• Is Part Of: Renewable & sustainable energy reviews. Volume 109(2019)
• Page Start: 367
• Page End: 385
• Publication Date: 2019-07
• Subjects: Solid electrolyte -- Ionic conductivity -- Electrochemical performance -- Stability -- Utmost limit; Li Lithium -- ASSLBs All-solid-state lithium batteries -- SPEs Solid polymer electrolytes -- NASICON Natrium superionic conductor -- thio-LISICON thio-Li super ionic conductor -- 3D Three dimensional -- RT Room temperature -- S-MWCNT Sulfur-coated carbon nanotubes -- LZP LiZr2(PO4)3 -- LTP LiTi2(PO4)3 -- LATP Li1.3Al0.3Ti1.7(PO4)3 -- LAGP Li1+xAlxGe2−x(PO4)3 -- LSTZ Li3/8Sr7/16Ta3/4Zr1/4O3 -- LSHT Li3/8Sr7/16Ta3/4Hf1/4O3 -- LSNZ Li3/8Sr7/16Nb3/4Zr1/4O3 -- LGLZO Li6.25Ga0.25La3Zr2O12 -- ORNL Oak Ridge National Laboratory -- LYZP Li1+xYxZr2-x(PO4)3 -- LGPS Li10GeP2S12 -- LLZO Li7La3Zr2O12 -- PEO Polyethylene oxide -- PEI Poly(ethylenimine) -- PEDA Polyester diacrylates -- PEO–PAN Polyacrylonitrile–polyethylene oxide -- PLD Pulsed laser deposition -- MOFs Metal organic frameworks -- PEOMA Poly(ethylene oxide) methyl ether methacrylate -- MBL α-methylene-γ-butyrolactone -- PEGDA Poly(ethylene glycol) diacrylate -- PEGDE Poly(ethylene glycol) diglycidyl ether -- PEOEC Poly(ethylene oxide-co-ethylene carbonate -- PTMC Poly(trimethylene carbonate) -- PEC Poly(ethylene carbonate) -- PPC Poly(propylene carbonate) -- CPPC Cellulose-supported PPC -- PMHS Polymethylhydrosiloxane -- ETPTA Ethoxylated trimethylolpropane triacrylate -- SLIC-SPEs Single lithium-ion conducting-based SPEs -- PEGM Poly(ethylene glycol) methyl ether methacrylate -- PEGDM Poly(ethylene glycol) methyl ether dimethacrylate -- PILs Poly(ionic liquid)s -- PDADMA TFSI Poly(diallyldimethylammonium) bis(trifluoromethanesulfonyl)imide -- P111i4FSI Trimethyl(isobutyl)phosphonium bis(fluorosulfonyl)imide -- NCPE Nanocomposite polymer electrolyte -- CNTs Carbon nanotubes -- MMT Montmorillonite -- HNT Halloysite nanotubes -- DR-XAS Depth-resolved X-ray absorption spectroscopy; Renewable energy sources -- Periodicals; Power resources -- Periodicals; Énergies renouvelables -- Périodiques; Ressources énergétiques -- Périodiques; 333.794
• DOI: 10.1016/j.rser.2019.04.035
• Languages: English
• ISSNs: 1364-0321

Abstract

Abstract: All-solid-state lithium batteries (ASSLBs) with solid electrolytes have attracted great attention for the replacement of traditional lithium batteries with liquid electrolytes due to their advantages such as high safety, excellent electrochemical cycling property and long-term stability. To date, various solid electrolytes including oxide, sulfide and polymer and organic-inorganic hybrid electrolytes have been developed for ASSLBs. Especially, the strategies to improve electrochemical performance especially ionic conductivity and stability of solid electrolytes have been widely studied. However, nowadays, ASSLBs are still not commercialized and used in our daily life. In this article, the situations of the solid electrolytes are critically reviewed, the main challenges and future prospective for the development of solid electrolytes are given and the utmost limits of those state-of-the-art solid electrolytes are analyzed. In addition, the electrode/electrolyte interface modification techniques to make ASSLBs achieving the excellent performance are evaluated. It is expected to provide a guidance for the development of novel solid electrolytes with higher ionic conductivity and environmental stability for ASSLBs. Highlights: State-of-the-art the solid electrolytes are critically reviewed. Main solid electrolytes including oxide, sulfide and polymer electrolytes are introduced. Strategies to improve ionic conductivity and stability of solid electrolytes are supposed. Main challenges and prospects for the development of novel solid electrolytes are given. The utmost limits of various solid electrolytes are analyzed.