Fire retardant action of zinc phosphinate and polyamide 11 blend containing lignin as a carbon source. (July 2018)

• Record Type: Journal Article
• Authors: Mandlekar, Neeraj; Malucelli, Giulio; Cayla, Aurelie; Rault, Francois; Giraud, Stephane; Salaün, Fabien; Guan, Jinping
• Is Part Of: Polymer degradation and stability. Volume 153(2018)
• Page Start: 63
• Page End: 74
• Publication Date: 2018-07
• Subjects: Lignin -- Polyamide 11 -- Zinc phosphinate -- Thermal decomposition -- Flame retardancy; Polymers -- Deterioration -- Periodicals; Stabilizing agents -- Periodicals; Polymères -- Dégradation -- Périodiques; Stabilisants -- Périodiques; 668.9
• DOI: 10.1016/j.polymdegradstab.2018.04.019
• Languages: English
• ISSNs: 0141-3910

Abstract

Abstract: This study investigates the thermal decomposition and fire behavior of zinc phosphinate (ZnP) in combination with low sulphonate content alkali lignin (LS) in a polyamide 11 (PA11) matrix. The influence of ZnP with LS on PA11 was assessed by using thermogravimetric analysis coupled with FTIR spectroscopy (TG-FTIR). Such decomposition products as hydrocarbons, amide and carbonyl units, phenolic and phosphinate compounds control the decomposition. The chemical structure of the condensed phase was evaluated by FTIR measurements carried out on the residues. The fire behavior was investigated using UL 94 vertical flame spread tests and cone calorimetry tests. In the ternary blends, the addition of LS promotes char formation as assessed by TG analyses; furthermore, ZnP contributes to flame inhibition mainly by radical trapping and partially by dilution of fuel, due to phosphinate ions and a small amount of phosphinic acid released in the gas phase. Besides, phosphate compounds are formed in the condensed phase. The combination of LS and ZnP enhanced flame-retardant properties due to the formation of a stable char layer with barrier features. Highlights: The influence of zinc phosphinate and low sulfonate alkali lignin on flame retardant properties of polyamide 11 blends was studied. Thermal decomposition and evolved gas analyses of the blends flame retarded with the two additives were investigated. The effect of the additives on smoke parameters and carbon monoxide production during forced combustion tests was assessed.