Covalently Grafting Cobalt Porphyrin onto Carbon Nanotubes for Efficient CO2 Electroreduction. Issue 20 (14th February 2019)

• Record Type: Journal Article
• Authors: Zhu, Minghui; Chen, Jiacheng; Huang, Libei; Ye, Ruquan; Xu, Jing; Han, Yi‐Fan
• Is Part Of: Angewandte Chemie international edition. Volume 58:Issue 20(2019)
• Page Start: 6595
• Page End: 6599
• Publication Date: 2019-02-14
• Subjects: carbon nanotubes -- CO2 reduction -- electroreduction -- grafting -- porphyrin; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201900499
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Molecular complexes with inexpensive transition‐metal centers have drawn extensive attention, as they show a high selectivity in the electrochemical conversion of CO2 to CO. In this work, we propose a new strategy to covalently graft cobalt porphyrin onto the surface of a carbon nanotube by a substitution reaction at the metal center. Material characterization and electrochemical studies reveal that the porphyrin molecules are well dispersed at a high loading of 10 wt. %. As a result, the turnover frequency for CO formation is improved by a factor of three compared to traditional physically‐mixed catalysts with the same cobalt content. This leads to an outstanding overall current density of 25.1 mA cm −2 and a Faradaic efficiency of 98.3 % at 490 mV overpotential with excellent long‐term stability. This work provides an effective pathway for the improvement of the performance of electrocatalysts that could inspire rational design of molecular catalysts in the future. Abstract : Highly dispersed : The covalent attachment of cobalt porphyrin onto carbon nanotubes is achieved by a substitution reaction at the metal center. This leads to large improvements in the efficiency of electrochemical CO2 reduction compared to systems where the compounds are physically mixed.