Methane Steam Reforming over an Ni-YSZ Solid Oxide Fuel Cell Anode in Stack Configuration. (24th June 2014)

• Record Type: Journal Article
• Authors: Mogensen, D.; Grunwaldt, J.-D.; Hendriksen, P. V.; Nielsen, J. U.; Dam-Johansen, K.
• Other Names: Mondal Subrata Academic Editor.
• Is Part Of: Journal of chemistry. Volume 2014(2014)
• Publication Date: 2014-06-24
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1155/2014/710391
• Languages: English
• ISSNs: 2090-9063

Abstract

Abstract : The kinetics of catalytic steam reforming of methane over an Ni-YSZ anode of a solid oxide fuel cell (SOFC) have been investigated with the cell placed in a stack configuration. In order to decrease the degree of conversion, a single cell stack with reduced area was used. Measurements were performed in the temperature range 600–800°C and the partial pressures of all reactants and products were varied. The obtained rates could be well fitted with a power law expression (r ∝ P C H 4 0.7 ). A simple model is presented which is capable of predicting the methane conversion in a stack configuration from intrinsic kinetics of the anode support material. The predictions are compared with the stack measurements presented here, and good agreement is observed.