Nanostructured CeO2 for selective-sensing and smart photocatalytic applications. Issue 13 (September 2018)

• Record Type: Journal Article
• Authors: Negi, K.; Kumar, M.; Singh, G.; Chauhan, S.; Chauhan, M.S.
• Is Part Of: Ceramics international. Volume 44:Issue 13(2018)
• Page Start: 15281
• Page End: 15289
• Publication Date: 2018-09
• Subjects: CeO2 nanostructure -- Photocatalyst -- Luminescence -- Chemical sensor -- Picric acid; Ceramics -- Periodicals; Céramique industrielle -- Périodiques; Ceramics; Periodicals; Electronic journals; 666
• DOI: 10.1016/j.ceramint.2018.05.172
• Languages: English
• ISSNs: 0272-8842

Abstract

Abstract: Well crystalline CeO2 nanoparticles have been successfully synthesized via solution combustion synthesis (SCS) using (NH4 )2 [Ce(NO3 )6 ] and C4 H6 O6 as oxidizer and fuel. The structural characteristics of as-synthesized material were investigated in terms of FESEM, HRTEM, EDS, XRD, FTIR and UV–Vis spectroscopy techniques. The surface area of synthesized CeO2 nanoscale material was obtained from BET plot. Results showed a pure, well-crystallized, flake-like mesoporous material to be formed with crystallite size of 18.86 nm. The focus of this study was to investigate the application of as-synthesized CeO2 nanomaterial for sensing and photocatalytic degradation of picric acid (PA) in its aqueous solution. It was found to be highly selective for PA detection in aqueous solution when compared with other aromatic compounds. Detection limit (0.52 µM) for PA when compared with earlier studies was found to be much better. In addition, 0.05 gm of as-synthesized CeO2 nanomaterial is found to be optimum amount ensuring maximum catalytic photodegradation of 10 ppm PA in aqueous solution. These experimental findings point out that as-synthesized CeO2 nanomaterial can be efficiently used as an effective chemical sensor and photocatalyst.