Consecutive addition esterification and hydrolysis of cyclic olefins catalyzed by multi-SO3H functionalized multi heteropolyanion-based ionic hybrids undersolvent-free conditions. Issue 7 (3rd April 2019)

• Record Type: Journal Article
• Authors: Zheng, Guocai; Li, Xinzhong
• Is Part Of: Synthetic communications. Volume 49:Issue 7(2019)
• Page Start: 933
• Page End: 941
• Publication Date: 2019-04-03
• Subjects: Addition esterification -- cyclic olefins -- heteropolyacid -- ionic hybrids; Organic compounds -- Synthesis -- Periodicals; Chemistry, Organic; Synthesis; 547.205
• DOI: 10.1080/00397911.2019.1580743
• Languages: English
• ISSNs: 0039-7911

Abstract

Abstract: An efficient protocol for the synthesis of cycloalkyl carboxylates and alcohols from cyclic olefins is described. The cyclic olefins were converted to corresponding target molecules under solvent-free conditions catalyzed by two novel multi-SO3 H functionalized multi heteropolyanion-based ionic hybrids through one-pot consecutive addition esterification and hydrolysis reactions. This approach has several advantages, including high yield, simple workup and simple purification. GRAPHICAL ABSTRACT: