Microwave assisted cross-coupling reactions using palladium nanoparticles in aqueous media. Issue 6 (19th March 2019)

• Record Type: Journal Article
• Authors: Dhara, Kalyan; Parasar, Bibudha; Patil, Avinash J.; Dash, Jyotirmayee
• Is Part Of: Synthetic communications. Volume 49:Issue 6(2019)
• Page Start: 859
• Page End: 868
• Publication Date: 2019-03-19
• Subjects: Glucose -- Heck coupling -- palladium nanoparticle -- recycling -- Suzuki coupling; Organic compounds -- Synthesis -- Periodicals; Chemistry, Organic; Synthesis; 547.205
• DOI: 10.1080/00397911.2019.1576203
• Languages: English
• ISSNs: 0039-7911

Abstract

Abstract: Glucose stabilized palladium nanoparticles (PdNPs) have been prepared and the application of NPs in catalyzing both Suzuki and Heck reactions has been explored in aqueous media under microwave conditions. Both electron-rich and electron-deficient aryl halides can be coupled with a variety of boronic acids and styrene to access a wide variety of biaryl compounds and substituted alkenes in good to excellent yields. The catalyst can be recycled and reused four times with minimally affecting the morphology and efficiency of the nanoparticles. A plausible reaction mechanism has been proposed. Graphical Abstract: