Improvement of Charge-Discharge Characteristics of the Mg-Ni Powder Electrodes at 55°C. (9th December 2013) - Chen, Kuan-Jen
Abstract : Magnesium-nickel (Mg-Ni) powders are used as the anode materials for secondary lithium (Li) ion batteries. Mg-Ni powders with ratios of 1 : 1 (Mg : Ni) are prepared and their structure and electrochemical behavior at room temperature and 55°C are investigated. The results show that adding Ni powders to Mg powders can reduce the charge-discharge capacities and improve cycling life. In charge-discharge cycle testing at 55°C, the Li ion concentration gradually increased with increasing the duration of electrochemical reactions, indicating that the charge-discharge capacities increase with increment of cycling number. The formation of a solid electrolyte interface (SEI) layer restrains Mg ions from dissolving into the electrolyte and thus improves the charge-discharge capacities at high temperature.