Iodine‐Mediated Synthesis of Aromatic Thioethers with Aromatic Amines and Sulfonyl Hydrazides in High Regioselectivity via C(sp2)H Bond Functionalization. Issue 2 (12th January 2016)

• Record Type: Journal Article
• Authors: Pang, Xiaobo; Xiang, Likui; Yang, Xiaodong; Yan, Rulong
• Is Part Of: Advanced synthesis & catalysis. Volume 358:Issue 2(2016)
• Page Start: 321
• Page End: 325
• Publication Date: 2016-01-12
• Subjects: aromatic thioethers -- CS bond formation -- hydrazines -- iodine -- regioselectivity -- sulfur; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201500943
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract: An iodine‐mediated synthesis of aromatic thioethers from aromatic amines and sulfonyl hydrazides via C( sp 2 )H bond functionalization and CS bond formation has been developed. In this procedure, various substituents on the sulfonyl hydrazides, such as alkyl, methoxyl, chloro, bromo and fluoro groups, and aromatic amines are tolerated in the thiolation which generates the desired products in moderate to good yields. Abstract :