Spectroscopic, Thermal, Electrochemical, and Antimicrobial Studies of Mononuclear Manganese(II) Ditolyldithiophosphates. (31st July 2013)

• Record Type: Journal Article
• Authors: Khajuria, Ruchi; Syed, Atiya; Kumar, Sandeep; Pandey, Sushil K.
• Other Names: Sovago Imre Academic Editor.
• Is Part Of: Bioinorganic chemistry and applications. Volume 2013(2013)
• Publication Date: 2013-07-31
• Subjects: Bioinorganic chemistry -- Periodicals; Bioinorganic chemistry; Biochemistry; Inorganic Chemistry; Chemistry, Bioinorganic; Periodicals; 572.51
• DOI: 10.1155/2013/261731
• Languages: English
• ISSNs: 1565-3633

Abstract

Abstract : New complexes of manganese(II) corresponding to [{ ( A r O ) 2 P S 2 } 2 Mn] and [{ ( A r O ) 2 P S 2 } 2 Mn.nL] (A r = o -, m -, p - CH3 C6 H4 and p -Cl- m -CH3 C6 H3 ; n = 1, L = N2 C12 H8, N2 C10 H8 ; n = 2, L = NC5 H5, P(C6 H5 )3 ) have been synthesized and characterized by microelemental analyses (C, H, and N), magnetic susceptibility, molar conductance, thermogravimetric, cyclic voltammetry, and spectral analyses including ESI mass spectrometry, IR, and UV-visible. The presence of a four-and-six coordinated Mn atoms has been established in the complexes and adducts, respectively. Antimicrobial screening of the complexes against gram negative bacteria E. coli, K. pneumonia, and P. aeruginosa and fungus S. rolfsii has shown potential bioactivity.