Anionic oxoborane and thioxoborane molecules supported by a 1, 2-bis(imino)acenaphthene ligand. Issue 20 (18th May 2021)

• Record Type: Journal Article
• Authors: Liu, Rui; Gao, Fangfang; Liu, Jingjing; Wei, Jing; Hou, Lei; Xie, Gang; Chen, Sanping; Zeng, Fanlong; Li, Anyang; Wang, Wenyuan
• Is Part Of: Dalton transactions. Volume 50:Issue 20(2021)
• Page Start: 6797
• Page End: 6801
• Publication Date: 2021-05-18
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d1dt01060c
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The isolable anionic oxoborane and thioxoborane, supported by a Dip-BIAN ligand, contain terminal doubly bonded BE (E = O, S) groups, respectively, in which only the BO group interacts with imidazolium via a hydrogen bond. Abstract : The isolable anionic oxoborane 3 and thioxoborane 4 have been assembled using a 1, 2-bis(imino)acenaphthene ligand (Dip-BIAN). Structural characterization and DFT calculations confirmed that two compounds contain terminal doubly bonded BE (E = O, S) groups, respectively, in which only the BO group is associated with imidazolium via a hydrogen bond.