Effect of TiO2 support on immobilization of cobalt porphyrin for electrochemical CO2 reduction. (30th July 2021)

• Record Type: Journal Article
• Authors: Gu, Shengshen; Marianov, Aleksei N.; Xu, Haimei; Jiang, Yijiao
• Is Part Of: Journal of materials science & technology. Volume 80(2021)
• Page Start: 20
• Page End: 27
• Publication Date: 2021-07-30
• Subjects: CO2 electroreduction -- Cobalt porphyrin -- Immobilization -- TiO2 support -- Carbon doping; Metals -- Periodicals; Materials science -- Periodicals; Materials science; Metals; Periodicals; 620.1105
• DOI: 10.1016/j.jmst.2020.09.053
• Languages: English
• ISSNs: 1005-0302

Abstract

Graphical abstract: This work studied the effect of TiO2 support for immobilization of molecular catalyst cobalt porphyrin on CO2 electroreduction. Both the crystalline phase and carbon doping exhibit significant influences on the catalytic performance. Highlights: Effect of TiO2 support for immobilized CoTPP on CO2 electroreduction was studied. Anatase TiO2 exhibits a better activity in CO2 electroreduction than rutile. Carbon doping in anatase further increases the activity of CO2 . electroreduction. The improved activity of C-doped anatase is attributed to the higher conductivity. Abstract: Electrochemical reduction of CO2 is a promising strategy to manage the global carbon balance by transforming CO2 into chemicals. The efficiency of CO2 electroreduction is largely dependent on the design of hybrid electrode where both support and catalyst govern the performance of the electrolyzer. In this work, TiO2 calcined at different temperatures, was used as a support for immobilization of cobalt tetraphenyl porphyrin (CoTPP) and its effect on CO2 reduction was studied. It is demonstrated that the crystalline phase of TiO2 and doping of TiO2 apparently affecting CO2 electroreduction. It is found that anatase phase exhibits higher activity and selectivity compared to rutile due to the enhanced conductivity which in turn enables faster electron transfer between the support and CoTPP. As for dopants, the carbon doping in anatase TiO2 is proven to further enhance its conductivity, consequently resulting in the enhanced performance. This study implies that the rational design of supports is important for the performance of the hybrid electrode towards electrochemical CO2 reduction.