Rhodium(iii)-catalyzed switchable C–H acylmethylation and annulation of 2, 2′-bipyridine derivatives with sulfoxonium ylides. Issue 19 (28th April 2021)

• Record Type: Journal Article
• Authors: Chen, Mengjia; Meng, Haifang; Yang, Fang; Wang, Yani; Chen, Chen; Zhu, Bolin
• Is Part Of: Organic & biomolecular chemistry. Volume 19:Issue 19(2021)
• Page Start: 4268
• Page End: 4271
• Publication Date: 2021-04-28
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/d1ob00590a
• Languages: English
• ISSNs: 1477-0520

Abstract

Abstract : A novel protocol for Rh(iii )-catalyzed switchable C–H acylmethylation and annulation of 2, 2′-bipyridine derivatives with sulfoxonium ylides was described. Abstract : A novel protocol for Rh(iii )-catalyzed switchable C–H acylmethylation and annulation of 2, 2′-bipyridine derivatives with sulfoxonium ylides is reported. This protocol provides a facile approach to synthesize structurally diverse acylmethylated 2, 2′-bipyridine derivatives and acyl pyrido[2, 3- a ]indolizines with a broad range of functional group tolerance.