Synthesis and Mesomorphic Properties of New Fluorinated Schiff Base Liquid Crystals. (16th January 2014)

• Record Type: Journal Article
• Authors: Ha, Sie-Tiong; Lee, Teck-Leong
• Other Names: Dou S. X. Academic Editor.; Higashimura H. Academic Editor.; Ji V. Academic Editor.; Li B. Academic Editor.
• Is Part Of: ISRN materials science. Volume 2014(2014)
• Publication Date: 2014-01-16
• Subjects: Materials science -- Periodicals; Materials science; Periodicals; 620.11
• DOI: 10.1155/2014/904657
• Languages: English
• ISSNs: 2090-6080

Abstract

Abstract : Two new compounds, 4-alkanoyloxybenzylidene-4 ′ -fluoroaniline and 4-fluorobenzylidene-4 ′ -n-alkanoyloxyaniline comprising a terminal fluorosubstituent were studied. The fluoro substituent contributes to the molecular polarizability, thus affecting intermolecular interactions and hence resulting in smectic mesomorphism. The mesomorphic properties were studied using differential scanning calorimetry and polarizing optical microscopy techniques. The mesomorphic properties of compounds studied are strongly dependent on the orientation of the imine (CH=N) linkage. The former Schiff base exhibited smectic A phase whereas the latter compound did not display any mesophase. Reversed imine linkage has caused depression of mesomorphic property in the compound studied (4-fluorobenzylidene-4 ′ -n-alkanoyloxyaniline). The mesomorphic properties of the present compounds were compared with other structurally related series to establish the chemical structure-mesomorphic property relationship.