Resorcin[4]arene-based multidentate phosphate ligands with superior binding affinity for nanocrystal surfaces. Issue 38 (13th April 2021)

• Record Type: Journal Article
• Authors: Nemat, Suren J.; Van den Eynden, Dietger; Deblock, Loren; Heilmann, Michael; Köster, Jesper M.; Parvizian, Mahsa; Tiefenbacher, Konrad; De Roo, Jonathan
• Is Part Of: Chemical communications. Volume 57:Issue 38(2021)
• Page Start: 4694
• Page End: 4697
• Publication Date: 2021-04-13
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d1cc00223f
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : We synthesized two resorcin[4]arene scaffolds with four phosphate binding groups. The superior binding affinity to nanocrystal surfaces is demonstrated using solution NMR spectroscopy and exceeds that of single phosphonates. Abstract : We designed and synthesized two resorcin[4]arene scaffolds with four phosphate binding groups. The ligands effectively bind in at least a tridentate fashion at low surface coverage. The superior binding affinity is demonstrated using solution NMR spectroscopy and exceeds that of single phosphonates.