Base promoted gem-difluoroolefination of alkyl triflones. Issue 39 (16th April 2021)
- Record Type:
- Journal Article
- Title:
- Base promoted gem-difluoroolefination of alkyl triflones. Issue 39 (16th April 2021)
- Main Title:
- Base promoted gem-difluoroolefination of alkyl triflones
- Authors:
- Yang, Ren-Yin
Wang, Hui
Xu, Bo - Abstract:
- Abstract : A new synthesis of gem -difluoroalkenes from readily available alkyl triflones and difluorocarbene precursors such as TMSCF2 Br has been reported. Abstract : A new synthesis of gem -difluoroalkenes from readily available alkyl triflones and difluorocarbene precursors such as TMSCF2 Br has been reported. The reaction, regardless of electronic effect, gives gem -difluoroalkenes in good to excellent yields. The mechanism may involve deprotonation of triflones, nucleophilic addition, and the elimination of SO2 CF3 .
- Is Part Of:
- Chemical communications. Volume 57:Issue 39(2021)
- Journal:
- Chemical communications
- Issue:
- Volume 57:Issue 39(2021)
- Issue Display:
- Volume 57, Issue 39 (2021)
- Year:
- 2021
- Volume:
- 57
- Issue:
- 39
- Issue Sort Value:
- 2021-0057-0039-0000
- Page Start:
- 4831
- Page End:
- 4834
- Publication Date:
- 2021-04-16
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d1cc01132d ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 16800.xml