All-carbon phosphoranes via difluorocarbene trapping. Issue 39 (16th April 2021)
- Record Type:
- Journal Article
- Title:
- All-carbon phosphoranes via difluorocarbene trapping. Issue 39 (16th April 2021)
- Main Title:
- All-carbon phosphoranes via difluorocarbene trapping
- Authors:
- Smirnov, Vladimir O.
Volodin, Alexander D.
Korlyukov, Alexander A.
Dilman, Alexander D. - Abstract:
- Abstract : A reaction of intramolecularly disposed phosphonium and phenoxide (or thiophenoxide) fragments with difluorocarbene affording all-carbon λ 5 -phosphoranes is described. Abstract : A reaction of intramolecularly disposed phosphonium and phenoxide (or thiophenoxide) fragments with difluorocarbene affording all-carbon λ 5 -phosphoranes is described. The presence of electron-withdrawing CHF2 -groups at the phosphonium center is important for the phosphorane formation. In a phosphorane, both phenyl groups located in the equatorial positions undergo 1, 2-P, C migration under thermal conditions.
- Is Part Of:
- Chemical communications. Volume 57:Issue 39(2021)
- Journal:
- Chemical communications
- Issue:
- Volume 57:Issue 39(2021)
- Issue Display:
- Volume 57, Issue 39 (2021)
- Year:
- 2021
- Volume:
- 57
- Issue:
- 39
- Issue Sort Value:
- 2021-0057-0039-0000
- Page Start:
- 4823
- Page End:
- 4826
- Publication Date:
- 2021-04-16
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d1cc01075a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 16800.xml