Organophosphorus decorated lithium borate and phosphate salts with extended π-conjugated backbone. Issue 19 (28th April 2021)

• Record Type: Journal Article
• Authors: Delgado Rosario, Emalyn; Rectenwald, Michael F.; Gaffen, Joshua R.; Rheingold, Arnold L.; Protasiewicz, John D.
• Is Part Of: Dalton transactions. Volume 50:Issue 19(2021)
• Page Start: 6667
• Page End: 6672
• Publication Date: 2021-04-28
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d1dt00601k
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Several new bifunctional salts, Li[B(DPN)2 ], Li[B(DPN)(ox)] and Li[P(DPN)3 ], have been prepared from the phosphorus(v )-containing chelating ligand 2, 3-dihydroxynaphthalene-1, 4-(tetraethyl)bis(phosphonate) (H2 -DPN ). Abstract : Several new bifunctional salts, Li[B(DPN)2 ], Li[B(DPN)(ox)] and Li[P(DPN)3 ], have been prepared from the phosphorus(v )-containing chelating ligand 2, 3-dihydroxynaphthalene-1, 4-(tetraethyl)bis(phosphonate) (H2 -DPN ). The new lithium salts were characterized by a variety of spectroscopic techniques. Both H2 -DPN and Li[B(DPN)2 ] have been structurally characterized by X-ray crystallographic methods. These salts are related to materials being examined for use in electrolyte solutions for lithium-ion battery (LIB) applications.