A facile in-situ coating strategy for Ni-rich cathode materials with improved electrochemical performance. (1st July 2021)

• Record Type: Journal Article
• Authors: Zhang, Xiang; Hu, Guorong; Cao, Yanbing; Peng, Zhongdong; Wang, Weigang; Tan, Chaopu; Wang, Yongzhi; Du, Ke
• Is Part Of: Electrochimica acta. Volume 383(2021)
• Publication Date: 2021-07-01
• Subjects: Lithium-ion batteries -- In-situ coating -- Ni-rich materials -- Lithium ion conductor; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2021.138297
• Languages: English
• ISSNs: 0013-4686

Abstract

Abstract: A facile in-situ hydrolytic coating strategy has been suggested to architecture LiAlSiO4 (LASO)-coated LiNi0.8 Co0.1 Mn0.1 O2 (LNCM) cathode material for lithium-ion batteries. Homogeneous LASO coating layer, as an one-dimensional lithium ion conductor, on the surface of LNCM is observed clearly and ascertained jointly by several testing methods. The effects of LASO coating layer on physicochemical properties, electrochemical properties and electrochemical kinetics of LNCM cathode material have been rigorously investigated by various tests. The cycling stability, rate capability and Li + ion diffusion rate are enhanced evidently after LASO coating. Moreover, the polarization, impedance increase and particles cracking after cycles under the high cut-off voltage are greatly improved. These effective and obvious improvements are ascribed to the LASO coating layer, which could effectively inhibit the occurrence of side reactions and HF erosion and provide a fast ion diffusion channel for lithium ions on the surface of LNCM.