A novel integration of a green power-to-ammonia to power system: Reversible solid oxide fuel cell for hydrogen and power production coupled with an ammonia synthesis unit. (20th May 2021)

• Record Type: Journal Article
• Authors: Mukelabai, Mulako Dean; Gillard, Jonathon M.; Patchigolla, Kumar
• Is Part Of: International journal of hydrogen energy. Volume 46:Number 35(2021)
• Page Start: 18546
• Page End: 18556
• Publication Date: 2021-05-20
• Subjects: Power-to-X -- Hydrogen -- Ammonia -- Electrolysis -- RSOFC -- Modelling; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2021.02.218
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: Renewable energy is a key solution in maintaining global warming below 2 °C. However, its intermittency necessitates the need for energy conversion technologies to meet demand when there are insufficient renewable energy resources. This study aims to tackle these challenges by thermo-electrochemical modelling and simulation of a reversible solid oxide fuel cell (RSOFC) and integration with the Haber Bosch process. The novelty of the proposed system is usage of nitrogen-rich fuel electrode exhaust gas for ammonia synthesis during fuel cell mode, which is usually combusted to prevent release of highly flammable hydrogen into the environment. RSOFC round-trip efficiencies of 41–53% have been attained when producing excess ammonia (144 kg NH3 /hr) for the market and in-house consumption respectively. The designed system has the lowest reported ammonia electricity consumption of 6.4–8.21 kWh/kg NH3, power-to-hydrogen, power-to-ammonia, and power-generation efficiencies of 80%, 55–71% and, 64–66%. Graphical abstract: Image 1 Highlights: P2A to power system enhances renewable energy usage by solving intermittency issues. Optimum P2A to power system design and operating parameters determined. Argon-free nitrogen resulting to non-limiting Haber Bosch recycle-loop fraction. Novel system has lowest reported ammonia synthesis electricity consumption. High power-to-ammonia efficiency attained, and excess ammonia available for market.