Metavalent Bonding in GeSe Leads to High Thermoelectric Performance. (22nd March 2021)

• Record Type: Journal Article
• Authors: Sarkar, Debattam; Roychowdhury, Subhajit; Arora, Raagya; Ghosh, Tanmoy; Vasdev, Aastha; Joseph, Boby; Sheet, Goutam; Waghmare, Umesh V.; Biswas, Kanishka
• Is Part Of: Angewandte Chemie. Volume 133:Number 18(2021)
• Page Start: 10438
• Page End: 10446
• Publication Date: 2021-03-22
• Subjects: low thermal conductivity -- metal selenide -- metavalent bonding -- soft phonon -- thermoelectrics; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202101283
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Orthorhombic GeSe is a promising thermoelectric material. However, large band gap and strong covalent bonding result in a low thermoelectric figure of merit, zT ≈0.2. Here, we demonstrate a maximum zT ≈1.35 at 627 K in p ‐type polycrystalline rhombohedral (GeSe)0.9 (AgBiTe2 )0.1 , which is the highest value reported among GeSe based materials. The rhombohedral phase is stable in ambient conditions for x =0.8–0.29 in (GeSe)1− x (AgBiTe2 ) x . The structural transformation accompanies change from covalent bonding in orthorhombic GeSe to metavalent bonding in rhombohedral (GeSe)1− x (AgBiTe2 ) x . (GeSe)0.9 (AgBiTe2 )0.1 has closely lying primary and secondary valence bands (within 0.25–0.30 eV), which results in high power factor 12.8 μW cm −1 K −2 at 627 K. It also exhibits intrinsically low lattice thermal conductivity (0.38 Wm −1 K −1 at 578 K). Theoretical phonon dispersion calculations reveal vicinity of a ferroelectric instability, with large anomalous Born effective charges and high optical dielectric constant, which, in concurrence with high effective coordination number, low band gap and moderate electrical conductivity, corroborate metavalent bonding in (GeSe)0.9 (AgBiTe2 )0.1 . We confirmed the presence of low energy phonon modes and local ferroelectric domains using heat capacity measurement (3–30 K) and switching spectroscopy in piezoresponse force microscopy, respectively. Abstract : The structural transformation of GeSe is associated with a change in nature of the chemical bonding from covalent bonding in pristine orthorhombic GeSe to metavalent bonding in rhombohedral (GeSe)1− x (AgBiTe2 ) x . Metavalent bonding and ferroelectric instability lead to high thermoelectric performance in the rhombohedral p ‐type polycrystalline (GeSe)1− x (AgBiTe2 ) x .