Π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons. (18th March 2021)

• Record Type: Journal Article
• Authors: Martínez‐Abadía, Marta; Strutyński, Karol; Lerma‐Berlanga, Belén; Stoppiello, Craig T.; Khlobystov, Andrei N.; Martí‐Gastaldo, Carlos; Saeki, Akinori; Melle‐Franco, Manuel; Mateo‐Alonso, Aurelio
• Is Part Of: Angewandte Chemie. Volume 133:Number 18(2021)
• Page Start: 10029
• Page End: 10034
• Publication Date: 2021-03-18
• Subjects: 3D covalent organic frameworks -- charge transport -- interpenetration -- non-planar aromatics -- polycyclic aromatic hydrocarbons; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202100434
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Three‐dimensional covalent organic frameworks (3D COFs) with a pcu topology have been obtained from distorted polycyclic aromatic hydrocarbons acting as triangular antiprismatic ( D 3 d ) nodes. Such 3D COFs are six‐fold interpenetrated as the result of interframework π‐stacking, which enable charge transport properties that are not expected for 3D COFs. Abstract : Three‐dimensional covalent organic frameworks (3D COFs) have been obtained from distorted polycyclic aromatic hydrocarbon nodes. Interframework π‐stacking enables charge transport properties that are not expected for 3D COFs.