Metalloligands based on Robson-type amino-thiophenolato macrocycles for assembly of heterotrimetallic complexes. Issue 17 (23rd April 2021)

• Record Type: Journal Article
• Authors: Schmorl, Sara; Naumov, Sergej; Abel, Bernd; Börner, Martin; Pöppl, Andreas; Kersting, Berthold
• Is Part Of: Dalton transactions. Volume 50:Issue 17(2021)
• Page Start: 5784
• Page End: 5788
• Publication Date: 2021-04-23
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d1dt00723h
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The bridging thiolate sulfur atoms in macrocyclic Ni and Co complexes exhibit metalloligand behaviour, forming adducts with various cuprate ions. Abstract : The ability of macrocyclic Co and Ni aminothiolate complexes to act as metalloligands towards cuprate ions was established. Adduct formation is enabled by a thiolate-to-Cu + charge transfer (CT) interaction giving stable heterotrimetallics with magnetic properties.