A direct synthesis of carboxylic acids via platinum-catalysed hydroxycarbonylation of olefins. Issue 8 (25th January 2021)
- Record Type:
- Journal Article
- Title:
- A direct synthesis of carboxylic acids via platinum-catalysed hydroxycarbonylation of olefins. Issue 8 (25th January 2021)
- Main Title:
- A direct synthesis of carboxylic acids via platinum-catalysed hydroxycarbonylation of olefins
- Authors:
- Schneider, Carolin
Franke, Robert
Jackstell, Ralf
Beller, Matthias - Abstract:
- Abstract : A selective platinum-catalysed hydroxycarbonylation of aliphatic olefins has been achieved. Abstract : The platinum-catalysed hydroxycarbonylation of olefins is reported for the first time. Using a combination of PtCl2 /2, 2′-bis( tert -butyl(pyridin-2-yl)phosphanyl)-1, 1′-binaphthalene (Neolephos) in the presence of sulfuric acid [0.6 M] in acetic acid selective carbonylation of terminal aliphatic olefins proceeds to good yields and selectivities to the corresponding carboxylic acids. Comparing the reactivity of different butenes (iso- and n -butenes), the terminal olefin can be selectively carbonylated.
- Is Part Of:
- Catalysis science & technology. Volume 11:Issue 8(2021)
- Journal:
- Catalysis science & technology
- Issue:
- Volume 11:Issue 8(2021)
- Issue Display:
- Volume 11, Issue 8 (2021)
- Year:
- 2021
- Volume:
- 11
- Issue:
- 8
- Issue Sort Value:
- 2021-0011-0008-0000
- Page Start:
- 2703
- Page End:
- 2707
- Publication Date:
- 2021-01-25
- Subjects:
- Catalysis -- Periodicals
541.395 - Journal URLs:
- http://pubs.rsc.org/en/Journals/JournalIssues/CY ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0cy02392b ↗
- Languages:
- English
- ISSNs:
- 2044-4753
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3090.943100
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 16642.xml