Improving Stability of LiCoO2 Cathode by Using Lithium Bis(Trifluoroborane)‐5‐Cyano‐2‐(Trifluoromethyl) Benzimidazolide as Additive. Issue 22 (9th January 2020)

• Record Type: Journal Article
• Authors: Admas Teshager, Minbale; Yang, Sheng‐Chiang; Hwang, Bing‐Joe; Lin, Shawn D.
• Is Part Of: ChemElectroChem. Volume 6:Issue 22(2019)
• Page Start: 5759
• Page End: 5764
• Publication Date: 2020-01-09
• Subjects: electrolyte additive -- LiCoO2 -- lithium-ion batteries -- LiPF6 -- in situ DRIFTS; Electrochemistry -- Periodicals; 541.37
• DOI: 10.1002/celc.201901686
• Languages: English
• ISSNs: 2196-0216

Abstract

Abstract: LiCoO2 is an important cathode material of commercial lithium‐ion batteries (LIBs) and therefore, improving the stability when LiCoO2 cathode is overcharged can have an immediate impact on commercial LIBs. A novel Li salt, lithium 5‐cyano‐bis(trifluoroborane)‐2‐(trifluoromethyl) benzimidazolide (Li[CBTBI]) is evidenced in this study as an effective additive for improving the electrode/electrolyte interface of LiCoO2 at high voltage operation condition. The presence of 2 % additive in commercial 1 M LiPF6 /EC+DEC lead to the formation of stable interface of LiCoO2 through cycles to 4.5 V, as demonstrated in cyclic voltammetry (CV). Electrochemical impedance spectroscopy (EIS) indicates a low‐impedance of the formed interface in the presence of the additive. Cyclability test also shows an improved stability in overcharging potential window by the presence of 2 % additive. In situ diffuse reflectance infrared Fourier‐transformed spectroscopy (DRIFTS) confirms the suppression of LiPF6 decomposition, delay of onset potential of solid electrolyte interphase (SEI) formation, and thin SEI comparing to that without the additive. The possible reasons of the advantageous effect of using Li salt additives are discussed. Abstract : A pinch of salt : A novel Li salt, lithium 5‐cyano‐bis(trifluoroborane)‐2‐(trifluoromethyl) benzimidazolide (Li[CBTBI]), is used as an additive to improve the stability LiCoO2 . With 2 % additive, the solid‐electrolyte interphase (SEI) exhibits low impedance. The additive leads to suppression of LiPF6 decomposition, delay of onset potential of SEI formation, and thin SEI.