Removal of Cr(VI) from Wastewater by a Novel Adsorbent of Magnetic Goethite: Adsorption Performance and Adsorbent Characterisation. Issue 47 (17th December 2019)

• Record Type: Journal Article
• Authors: Liu, Zhanmeng; Chen, Gang; Xu, Lichun; Hu, Fengping; Duan, XianYue
• Is Part Of: ChemistrySelect. Volume 4:Issue 47(2019)
• Page Start: 13817
• Page End: 13827
• Publication Date: 2019-12-17
• Subjects: Adsorption -- Cr(VI) -- Goethite -- Magnetic goethite -- Magnetic properties; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.201904125
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: A novel adsorbent of magnetic goethite was prepared by neutralisation hydrolysis and employed for Cr(VI) adsorption from aqueous solution. The magnetic goethite adsorbent was characterised by using scanning electron microscopy (SEM), X‐ray diffractometer (XRD), vibrating sample magnetometer (VSM), fourier transform infrared (FTIR), brunauer‐Emmett‐Teller (BET) and X‐ray photoelectron spectroscopy (XPS) method. VSM showed that the prepared adsorbents are super‐paramagnetic iron hydroxide. FTIR spectra revealed that magnetic goethite have ‐OH and other functional groups. The effects of various factors, including pH, adsorbent dosage, initial concentration, and ion concentration, were evaluated. Under the conditions of pH 3, 4 g/L magnetic goethite, 20 mg/L Cr(VI) concentration, and 0.01 mol/L NaNO3, the removal efficiency of Cr (VI) reached 88.2% and the adsorption capacity of the adsorbent reached 4.32 mg/g. The adsorption kinetic tests showed that the adsorption of Cr(VI) on the adsorbent matched well with pseudo‐second‐order kinetics, indicating the occurrence of chemisorption. The fitting of the Langmuir isotherm model showed that the adsorption of Cr(VI) on magnetic goethite was monolayer adsorption. On the other hand, thermodynamic studies conjectured that the adsorption processes of magnetic goethite for Cr(VI) was endothermic and spontaneous. These results suggest that magnetic goethite has great potential for the removal of heavy metals from wastewater. Abstract : In this study, magnetic goethite based on nano‐Fe3 O4 was synthesised via a facile and low‐cost green method. The adsorption isotherm and kinetic tests showed the adsorption of Cr(VI) on magnetic goethite was monolayer chemisorption. On the other hand, thermodynamic studies conjectured that the adsorption processes of magnetic goethite for Cr(VI) was endothermic and spontaneous. These results suggest that magnetic goethite has great potential for the removal of heavy metals from wastewater.