Nanoindentation analysis of oriented polypropylene: Influence of elastic properties in tension and compression. (29th August 2018)

• Record Type: Journal Article
• Authors: Vgenopoulos, D.; Sweeney, J.; Grant, C.A.; Thompson, G.P.; Spencer, P.E.; Caton-Rose, P.; Coates, P.D.
• Is Part Of: Polymer. Volume 151(2018)
• Page Start: 197
• Page End: 207
• Publication Date: 2018-08-29
• Subjects: Polypropylene -- Die-drawing -- Nanoindentation -- Finite elements; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; 547.7
• DOI: 10.1016/j.polymer.2018.07.080
• Languages: English
• ISSNs: 0032-3861

Abstract

Abstract: Polypropylene has been oriented by solid-phase deformation processing to draw ratios up to ∼16, increasing tensile stiffness along the draw direction by factors up to 12. Nanoindentation of these materials showed that moduli obtained for indenter tip motion along the drawing direction (3) into to 1–2 plane (axial indentation) were up to 60% higher than for indenter tip motion along the 2 direction into the 1–3 plane (transverse indentation). In static tests, tensile and compressive determinations of elastic modulus gave results differing by factors up to ∼5 for strain along the draw direction. A material model incorporating both orthotropic elasticity and tension/compression asymmetry was developed for use with Finite Element simulations. Elastic constants for the oriented polypropylene were obtained by combining static testing and published ultrasonic data, and used as input for nanoindentation simulations that were quantitatively successful. The significance of the tension/compression asymmetry was demonstrated by comparing these predictions with those obtained using tensile data only, which gave predictions of indentation modulus higher by up to 70%. Graphical abstract: Image Highlights: Analysis of nanoindentation is developed for elastic properties of oriented polymer. Elastic anisotropy drives requirement for non-standard analysis. Tension-compression asymmetry also needs to be included in analysis. FE modelling that includes both these effects is successfully applied to PP.