Brush-modified materials: Control of molecular architecture, assembly behavior, properties and applications. (January 2020)

• Record Type: Journal Article
• Authors: Yan, Jiajun; Bockstaller, Michael R.; Matyjaszewski, Krzysztof
• Is Part Of: Progress in polymer science. Volume 100(2020)
• Publication Date: 2020-01
• Subjects: a Length of a repeat -- AFM Atomic force microscopy -- AP Anionic polymerization -- A(R)GET Activator (re)generation by electron transfer -- ATRP Atom transfer radical polymerization -- -b- -Block- -- bcc Body-centered cubic -- BCP Block copolymer -- BiBADA 12-(2-Bromoisobutyramido)dodecanoic acid -- BMWD Bimodal molecular weight distribution -- BSA Bovine serum albumin -- CB Conduction band -- CD Cyclodextrin -- CPB Concentrated polymer brush -- CPDB 4-(4-Cyanopentanoic acid) dithiobenzoate -- CRP Controlled radical polymerization -- CT Computed tomography -- CTA Chain-transfer agent -- CuAAC Copper-catalyzed azide-alkyne cycloaddition -- d Diameter OR brush height -- Đ Dispersity -- dc Diamond cubic -- DC Daoud and Cotton -- DEPN N-tert-butyl-N-(1-diethylphosphono-2, 2-dimethylpropyl) nitroxide -- DFT Density functional theory -- dip Interparticle distance -- DLS Dynamic light scattering -- DMSO Dimethyl sulfoxide -- DNA Deoxyribonucleic acid -- DOTA 1, 4, 7, 10-Tetraazacyclododecane-1, 4, 7, 10-tetraacetic acid -- DP Degree of polymerization -- eATRP Electrochemically-mediated atom transfer radical polymerization -- EGaIn Eutectic gallium-indium alloy -- Epc Cathodic peak potential -- f Number of chains -- fx Weight fraction of x -- fcc Face-centered cubic -- FRP (conventional) free radical polymerization -- h (brush) height -- hcp Hexagonal close packed -- HOMO Highest occupied molecular orbital -- hν Photoirradiation -- ICAR Initiator for continuous activator regeneration -- IgG Immunoglobin G -- KIc Stress intensity factor for mode I fracture -- l Segment length -- LAP Living anionic polymerization -- LC Liquid crystal -- LCP Living cationic polymerization -- LCST Lower critical solution temperature -- LED Light-emitting diode -- MADIX Macromolecular design via interchange of xanthates -- Me6 TREN Tris(2-(dimethylamino)ethyl)amine -- Mn Number-average molecular weight -- MRI Magnetic resonance imaging -- Mw Weight-average molecular weight -- MW Molecular weight -- MWC Millner, Witten, and Cates -- MWD Molecular weight distribution -- n Refractive index -- N Degree of polymerization -- NA Avogadro number -- NHS N-hydoxysuccinimide -- NIR Near infrared -- NMP Nitroxide-mediated polymerization -- NP Nanoparticle -- OEGA Oligo(ethylene glycol acrylate) -- OMRP Organometallic-mediated radical polymerization -- P2VP Poly(2-vinylpyridine) -- P4VP Poly(4-vinylpyridine) -- PAA Poly(acrylic acid) -- PAAm Polyacrylamide -- PAN Polyacrylonitrile -- PAPTAC Poly(3-(acrylamido)propyl(trimethyl)ammonium chloride) -- PBA Poly(n-butyl acrylate) -- PBiBEM Poly(2-(2-bromoisobutyryloxy)ethyl methacrylate) -- PDMAEMA Poly(2-(dimethylamino)ethyl methacrylate) -- PDMS Poly(dimethylsiloxane) -- PEA Poly(ethyl acrylate) -- PEDOT Poly(3, 4-ethylenedioxythiophene) -- PEG Poly(ethylene glycol) -- PEGMA Poly(ethylene glycol) methacrylate -- PenG Penicillin G -- PEO Poly(ethylene oxide) -- PET Photoinduced electron transfer -- PGMA Poly(glycidyl methacrylate) -- PHEMA Poly(2-hydroxyethyl methacrylate) -- photoATRP Photochemically-mediated atom transfer radical polymerization -- PIMP Photoiniferter-mediated polymerization -- PMA Poly(methyl acrylate) -- PMAA Poly(methacrylic acid) -- PMDETA N, N, N', N'', N''-pentamethyldiethylenetriamine -- PMMA Poly(methyl methacrylate) -- PNIPAM Poly(N-isopropylacrylamide) -- POSS Polyhedral oligomeric silsesquioxane -- PPE Poly(phenylene ethynylene) -- PPG Poly(propylene glycol) -- PRISM Polymer reference interaction site model -- PS Polystyrene -- PSS Poly(4-styrene sulfonate) -- PSAN Poly(styrene-co-acrylonitrile) -- PtBA Poly(tert-butyl acrylate) -- PVP Poly(N-vinyl-2-pyrrolidone) -- QD Quantum dot -- QLED Quantum dot light emitting diode -- R Radius -- RAFT Reversible addition-fragmentation chain-transfer -- RDRP Reversible deactivation radical polymerization -- Rg Radius of gyration -- RITP Reversible iodine transfer polymerization -- RNA Deoxyribonucleic acid -- ROMP Ring-opening metathesis polymerization -- ROP Ring-opening polymerization -- SAM Self-assembled monolayer -- SARA Supplemental activator and reducing agent -- SCFT Self-consistent field theory -- SCVP Self-condensing vinyl polymerization -- SDPB Semidilute polymer brush -- SEC Size-exclusion chromatography -- SFRP Stable free radical mediated polymerization -- SI- Surface-initiated -- SPIO Superparamagnetic nanoparticles -- S-RAFT Surface reversible addition-fragmentation chain-transfer -- St Styrene -- TEM Transmission electron microscopy -- TERP Organotellerium-mediated radical polymerization -- TFA Trifluoroacetic acid -- Tg Glass transition temperature -- TGA Thermogravimetric analysis -- THF Tetrahydrofuran -- TMS Trimethylsilyl -- TPMA Tris(2-pyridinylmethyl)amine -- TSI Thermal self-initiation -- UCL Upconversion luminescence -- U(r) Repulsion potential -- VB Valence band -- WZ Wijmans and Zhulina -- ε Permittivity -- λ Wavelength -- v Excluded volume parameter -- V(r) Effective pair interaction potential -- ξ(r) Size of a thermal blob -- χ Flory Huggins interaction parameter -- ρ (Bulk) density -- ρs Grafting density (on surface) -- σ Grafting density -- ϕ Volume fraction; Polymer brush -- Hybrid materials -- Inorganic nanoparticles -- Reversible deactivation radical polymerization -- ATRP; Polymers -- Periodicals; Polymerization -- Periodicals; Polymers -- Industrial applications -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; 547.7
• DOI: 10.1016/j.progpolymsci.2019.101180
• Languages: English
• ISSNs: 0079-6700

Abstract

Graphical abstract: Abstract: Recent progress in surface-initiated polymerization enables the deliberate polymer modification of nanoscopic surfaces with high levels of precision. This has given rise to the development of brush particle-based materials (sometimes referred to as 'hairy nanoparticles') that are formed by tethering of polymer chains to the surface of nanoparticle-like objects. Brush particles have attracted interest as model systems to understand the effect of surface modification on the structure and interactions in polymer modified colloidal systems (which play a role across fields as diverse as functional coatings, cosmetics, foods or pharmaceuticals) but also as building blocks for the assembly of 'one-component hybrid materials' that exhibit unprecedented property combinations, not realizable in classical composite materials. This review presents a summary and analysis of the developments in 'particle brush materials'. The evolution of synthetic methodologies from the original pioneering work to emerging trends and opportunities in the field of brush synthesis is presented first. Subsequently, the effect of brush architecture on the structure, interaction and assembly of brush particles both with and without a matrix is discussed. Finally, recent advances in the development of functional hybrid materials with applications in energy, catalysis, sensing and other areas is presented.