Carbon felt electrodes for redox flow battery: Impact of compression on transport properties. (December 2019)

• Record Type: Journal Article
• Authors: Banerjee, Rupak; Bevilacqua, Nico; Mohseninia, Arezou; Wiedemann, Benjamin; Wilhelm, Florian; Scholta, Joachim; Zeis, Roswitha
• Is Part Of: Journal of energy storage. Volume 26(2019)
• Publication Date: 2019-12
• Subjects: Redox flow batteries -- Carbon felt electrodes -- Pore network modeling -- Transport properties -- Compression -- Electrical conductivity -- Synchrotron X-ray radiography; Energy storage -- Periodicals; Energy storage -- Research -- Periodicals; 621.3126
• DOI: 10.1016/j.est.2019.100997
• Languages: English
• ISSNs: 2352-152X

Abstract

Highlights: Impact of compression of felt electrodes on transport properties is presented. Carbon felt materials compressed up to 67% and imaged using X-ray tomography. Electrical conductivity decreased strongly in the first 20% compression. Single-phase transport properties decreased with increasing compression. Pressure to reach breakthrough increased, but no change to reach full saturation. Abstract: In a flow battery setup, carbon felt materials are compressed to obtain higher performance from the battery. In this work, a commercially available carbon felt material, commonly used as electrodes in Vanadium Redox Flow Battery setups was evaluated for the transport properties (diffusivity, permeability, pressure drop required for maintaining flow, among others) while under seven set levels of compression, using an image analysis coupled with pore network modeling approach. X-ray computed tomography has been used to obtain the microstructure of a commercially available electrode under compressed conditions. An open-source pore network modeling tool, OpenPNM has been used to investigate the transport properties of the porous felt material at each of the set compression levels. The results from the modeling are compared against experimentally obtained electrolyte transport patterns visualized using synchrotron X-ray radiography. The electrical resistance of the carbon felt electrode was measured experimentally using a four-probe method. The compression resulted in a 58% reduction in permeability, and a 25% reduction in single-phase diffusion. This combination of ex-situ characterization of the electrical and fluid transport through the electrodes provides valuable data for modeling flow battery systems, and validating hypothesis from in situ testing. Graphical abstract: Image, graphical abstract