A study of densified biochar as carbon source in the silicon and ferrosilicon production. (15th August 2019)

• Record Type: Journal Article
• Authors: Riva, Lorenzo; Surup, Gerrit Ralf; Buø, Therese Videm; Nielsen, Henrik Kofoed
• Is Part Of: Energy. Volume 181(2019)
• Page Start: 985
• Page End: 996
• Publication Date: 2019-08-15
• Subjects: Biochar -- Pyrolysis oil -- Densification -- Silicon production -- Ferrosilicon production -- Carbon neutrality; daf dry ash free basis -- db dry basis -- DTG derivative thermogravimetry -- SEM scanning electrode microscope -- SHT second heat treatment -- TGA thermogravimetric analysis -- TS tensile strength -- wb wet basis; Power resources -- Periodicals; Power (Mechanics) -- Periodicals; Energy consumption -- Periodicals; 333.7905
• DOI: 10.1016/j.energy.2019.06.013
• Languages: English
• ISSNs: 0360-5442

Abstract

Abstract: Biochar pellets were investigated as renewable reducing agents in substitution of coal and coke in the silicon and ferrosilicon production, where a high reactivity, good mechanical properties and low feedstock costs are appreciated. The usage of pyrolysis oil as binder was investigated as way to improve the quality of the pellets. Norway spruce biochar produced at 500, 800 and 1100 °C, was pelletized blended with pyrolysis oil and lignosulphonate. A second heat treatment was carried out at the same temperatures to evaluate the interaction between biochar and pyrolysis oil and to imitate the thermal stability of the pellets when used in a furnace. Density, tensile strength and mechanical durability were analyzed before and after the second heat treatment. The CO2 reactivity was investigated under non-steady conditions. It was observed that the pellet quality is affected by the pyrolysis temperature, showing a relevant difference in properties between 500 °C and 800 °C. The combination of lignosulphonate and pyrolysis oil improved considerably the density and mechanical durability of the pellets. By the second heat treatment, the quality of the pellets was bettered significantly. Densification seems to reduce CO2 reactivity; however, pellets showed a still high reactivity. Highlights: Pyrolysis temperature strongly affects the quality of biochar pellets. Pyrolysis oil as binder improves mechanical properties of biochar pellets. Heat treatment of produced biochar pellets improves mechanical properties further. Densification affects slightly the CO2 reactivity of biochar. Densification makes biochar more attractive for metallurgical applications.