Correlating electrochemical impedance with hierarchical structure for porous carbon-based supercapacitors using a truncated transmission line model. (10th September 2018)

• Record Type: Journal Article
• Authors: Abouelamaiem, Dina Ibrahim; He, Guanjie; Neville, Tobias P.; Patel, Drasti; Ji, Shan; Wang, Rongfang; Parkin, Ivan P.; Jorge, Ana Belen; Titirici, Maria-Magdalena; Shearing, Paul R.; Brett, Daniel J.L.
• Is Part Of: Electrochimica acta. Volume 284(2018)
• Page Start: 597
• Page End: 608
• Publication Date: 2018-09-10
• Subjects: Electrochemical impedance spectroscopy -- Equivalent circuit -- Pore size distribution -- Relaxation time -- Transmission line model; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2018.07.190
• Languages: English
• ISSNs: 0013-4686

Abstract

Abstract: This work considers the relationship between the morphology of porous carbon materials used for supercapacitors and the electrochemical impedance spectroscopy (EIS) response. EIS is a powerful tool that can be used to study the porous 3-dimensional electrode behavior in different electrochemical systems. Porous carbons prepared by treatment of cellulose with different compositions of potassium hydroxide (KOH) were used as model systems to investigate the form vs. electrochemical function relationship. A simple equivalent circuit that represents the electrochemical impedance behavior over a wide range of frequencies was designed. The associated impedances with the bulk electrolyte, Faradaic electrode processes and different pore size ranges were investigated using a truncated version of the standard transmission line model. The analysis considers the requirements of porous materials as electrodes in supercapacitor applications, reasons for their non-ideal performance and the concept of 'best capacitance' behavior in different frequency ranges. Graphical abstract: The electrolyte ions penetrate the macropores, into the mesopores and finally reach the micropores. The capacitance measured by impedance spectroscopy is a function of frequency and porous structure. Image 1 Highlights: Impedance spectroscopy is employed to study frequency response of porous electrodes. Potassium hydroxide-activated carbons are used as model systems in supercapacitors. A simple equivalent circuit is proposed based on the transmission line model. Frequency-dependant relaxation times, capacitive and resistive elements are evaluated. Non-ideal capacitive performance of various porous carbon electrodes is investigated.