A chiroptical approach for the absolute stereochemical determination of P-stereogenic centers. Issue 5 (15th December 2020)
- Record Type:
- Journal Article
- Title:
- A chiroptical approach for the absolute stereochemical determination of P-stereogenic centers. Issue 5 (15th December 2020)
- Main Title:
- A chiroptical approach for the absolute stereochemical determination of P-stereogenic centers
- Authors:
- Chakraborty, Debarshi
Gholami, Hadi
Sarkar, Aritra
Joyce, Leo A.
Jackson, James E.
Borhan, Babak - Abstract:
- Abstract : A simple chiroptical solution for the absolute stereochemical determination for asymmetric phosphorus V stereocenters is presented. Abstract : A simple chiroptical solution for the absolute stereochemical determination for asymmetric phosphorus V stereocenters is presented. Strong coordination of the phosphorus oxide with the Zn-metallo center of the racemic host Zn-MAPOL 2 leads to an induced axial chirality of the host, yielding a strong ECCD signal. A mnemonic is proposed to correlate the asymmetry of the guest molecule with the observed ECCD signal.
- Is Part Of:
- Chemical science. Volume 12:Issue 5(2021)
- Journal:
- Chemical science
- Issue:
- Volume 12:Issue 5(2021)
- Issue Display:
- Volume 12, Issue 5 (2021)
- Year:
- 2021
- Volume:
- 12
- Issue:
- 5
- Issue Sort Value:
- 2021-0012-0005-0000
- Page Start:
- 1750
- Page End:
- 1755
- Publication Date:
- 2020-12-15
- Subjects:
- Chemistry -- Periodicals
540.5 - Journal URLs:
- http://pubs.rsc.org/en/Journals/JournalIssues/SC ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0sc02940h ↗
- Languages:
- English
- ISSNs:
- 2041-6520
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3151.490000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 16561.xml