Frontispiece: Intermediate Valence States in Lanthanide Compounds. Issue 23 (22nd April 2021)

• Record Type: Journal Article
• Authors: Tricoire, Maxime; Mahieu, Nolwenn; Simler, Thomas; Nocton, Grégory
• Is Part Of: Chemistry. Volume 27:Issue 23(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-04-22
• Subjects: intermediate valence -- lanthanides -- organometallics -- spectroscopy -- theoretical computations; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.202182363
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract : Intermediate valence states in lanthanide compounds have often resulted in unexpected or puzzling spectroscopic and magnetic properties. In their Minireview on page 6860, Thomas Simler, Grégory Nocton and colleagues highlight the different singularities that have been observed among lanthanide complexes, detail the models used to rationalise them and show how such electronic effects may be adjusted depending on energy and symmetry considerations.