Electrochemical studies of novel thiophene-tetrazine donor-acceptor hybrids. (30th March 2021)

• Record Type: Journal Article
• Authors: Pluczyk-Malek, Sandra; Nastula, Dawid; Honisz, Damian; Jedrysiak, Rafal; Lapkowski, Mieczyslaw; Richardson, Christopher; Wagner, Pawel
• Is Part Of: Tetrahedron letters. Volume 68(2021)
• Publication Date: 2021-03-30
• Subjects: s-Tetrazine -- Electrochemistry -- Thiophene -- Electron paramagnetic resonance (EPR); Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1016/j.tetlet.2021.152905
• Languages: English
• ISSNs: 0040-4039

Abstract

Graphical abstract: Highlights: New donor-acceptor thiophene-tetrazine compounds. Electrochemical and EPR spectroelectrochemical study of s -tetrazine compounds. Density functional theory (TDDFT) calculations support electronic structure. Supramolecular structure analysis via single crystal X-ray diffraction. Abstract: The compartmentalization of molecular properties is achievable in thiophene-tetrazine assemblies featuring non-conjugating spacer-groups between electron rich thiophene rings and electron deficient s -tetrazine rings. The assemblies have been studied electrochemically and spectro-electrochemically and our results are supported by TDDFT computations.