Front Cover: Heterobimetallic Carbene Complexes Bearing Cyclometalated IrIII/RhIII and Mixed NHC∧ Py/PPh3 Coordinated PdII Centers: Structures and Tandem Catalysis (Eur. J. Inorg. Chem. 12/2021). Issue 12 (23rd February 2021)

• Record Type: Journal Article
• Authors: Majumder, Adhir; Nath Saha, Tarak; Majumder, Niladri; Naskar, Rajat; Pal, Kuntal; Maity, Ramananda
• Is Part Of: European journal of inorganic chemistry. Issue 12(2021)
• Page Start: 1103
• Page End: 1103
• Publication Date: 2021-02-23
• Subjects: Carbene ligands -- Heterobimetallic complexes -- Structure elucidation -- Tandem catalysis -- Transfer hydrogenation; Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.202100135
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract : The Front Cover shows the combined action of two different metal centers in heterobimetallic M III −Pd II (M=Rh, Ir) complexes, featuring cyclometalated M III and mixed NHC ∧ Py/PPh3 coordinated Pd II centers, during tandem Suzuki‐Miyaura/transfer hydrogenation reactions. The heterobimetallic complex, bearing cyclometalated Ir III and mixed NHC ∧ PPh3 donor ligands at the Pd II center, shows excellent selectivity for 4‐biphenylmethanol in the tandem reaction. More information can be found in the Full Paper by R. Maity and co‐workers .