Carbon Dots Assisted Synthesis of Gold Nanoparticles and Their Catalytic Activity in 4‐Nitrophenol Reduction. Issue 12 (26th March 2019)

• Record Type: Journal Article
• Authors: Ghosh, Souvik; Satapathy, Smith S.; Ghosh, Kowsik; Jauhari, Smita; Panda, Subhendu K.; Si, Satyabrata
• Is Part Of: ChemistrySelect. Volume 4:Issue 12(2019)
• Page Start: 3416
• Page End: 3422
• Publication Date: 2019-03-26
• Subjects: Carbon Dots -- Catalysis -- Gold Nanoparticles -- Hybrid Nanostructures -- Nitrophenol reduction; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.201804040
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: A novel biocompatible carbon nanoparticles, i. e., carbon dots (CDs) are prepared from cheap organic precursors and are used to synthesize gold nanoparticles (AuNPs). The formation of CDs are confirmed from their absorption and emission properties. The CDs not only acts as reducing agent but also stabilizes the resulting AuNPs. The high stabilizing effect of CDs can be attributed to their hydrophilic surfaces due to the presence of ‐C=O, ‐OH, etc. functional group as confirmed from FTIR spectral analysis. Basically, two types of AuNPs are observed, one is decahedron type particles and the other one is triangular plates. The size of decahedron type AuNPs are measured to be ∼ 30 nm, whereas those of triangular plates are ∼ 100 nm. These mixture of AuNPs are used to study a model catalytic reaction, i. e., reduction of 4‐nitrophenol by NaBH4 in which the reaction is completed in 5 Mins and the reaction follows the first order kinetics with a first order rate constant of 1.28 min −1 . Moreover, the resulting AuNPs can be reused for further reactions and up to 4 cycles it has been observed that the efficiency of conversion remains ∼100% with this AuNPs catalyst. Thus, functional CDs not only catalyse the formation of AuNPs, but also give them enough stability for catalytic applications in many organic transformation reactions. Abstract : Functional carbon dots (CDs) are prepared from cheap organic precursors and are used to synthesize gold nanoparticles (AuNPs). The CDs not only acts as reducing agent but also stabilizes the resulting AuNPs, which can be attributed to their hydrophilic surfaces. Two types of AuNPs are observed, decahedron type particles (∼30 nm) and the triangular plates (∼100 nm). The resulting AuNPs catalyze the reduction of 4‐nitrophenol in 5 Mins with a first order rate constant of 1.28 min −1 and can be reused for further reactions at least up to 4 cycles without hampering their conversion efficiency. Thus, functional CDs not only catalyse the formation of AuNPs, but also give them enough stability for catalytic applications in organic transformation reactions.