The influencing role of oxophilicity and surface area of the catalyst for electrochemical methanol oxidation reaction: a case study. (10th November 2019)

• Record Type: Journal Article
• Authors: Siwal, Samarjeet; Devi, Nishu; Perla, Venkata; Barik, Rasmita; Ghosh, Sarit; Mallick, Kaushik
• Is Part Of: Materials research innovations. Volume 23:Number 7(2019)
• Page Start: 440
• Page End: 447
• Publication Date: 2019-11-10
• Subjects: 'Zinc-oxide modified carbon-nitride' -- palladium nanoparticles -- methanol oxidation; Materials -- Research -- Periodicals; Matériaux -- Recherche -- Périodiques; 620.1105
• DOI: 10.1080/14328917.2018.1533268
• Languages: English
• ISSNs: 1432-8917

Abstract

ABSTRACT: The zinc oxide modified carbon nitride was synthesized by applying a high temperature in-situ route and has been used as a support matrix for the palladium nanoparticles. The resultant material was analyzed by the optical and the surface characterization techniques, which offered the information about the interaction between carbon nitride and zinc oxide. For comparison, we have synthesized carbon nitride alone and also applied as a support material for palladium nanoparticles. Both the synthesized materials were successfully used as electrocatalyst for the methanol oxidation reaction under the alkaline media. The stability and the tolerance of the synthesized catalysts have been thoroughly studied and described in this report, in connection with the title reaction, on the basis of oxophilicity and the surface area.