Atmospheric Chemistry of tert-butylamine and AMP. (July 2017)

• Record Type: Journal Article
• Authors: Antonsen, Simen; Bunkan, Arne J.C.; D'Anna, Barbara; Eichler, Philipp; Farren, Naomi; Hallquist, Mattias; Hamilton, Jacquiline F.; Kvarnliden, Hampus; Mikoviny, Tomáš; Müller, Markus; Nielsen, Claus J.; Stenstrøm, Yngve; Tan, Wen; Wisthaler, Armin; Zhu, Liang
• Is Part Of: Energy procedia. Volume 114(2017)
• Page Start: 1026
• Page End: 1032
• Publication Date: 2017-07
• Subjects: Amines -- nitramines -- atmospheric chemistry -- photo-oxidation; Power resources -- Congresses; Power resources -- Periodicals; Power resources; Conference proceedings; Periodicals; 333.7905
• DOI: 10.1016/j.egypro.2017.03.1248
• Languages: English
• ISSNs: 1876-6102

Abstract

Abstract: The atmospheric chemistry of (CH3 )3 CNH2 ( tert -butylamine, t BA) and (CH3 )2 (CH2 OH)CNH2 (2-amino-2-methyl-1-propanol, AMP) has been studied by quantum chemistry methods and in photo-oxidation experiments in the EUPHORE chamber in Valencia (Spain). Aerosol formation and composition has been quantified. Yields of nitramines and other products in the photo-oxidations have been determined and complete photo-oxidation schemes including branching between the major reaction routes have been obtained.