Maximized Schottky Effect: The Ultrafine V2O3/Ni Heterojunctions Repeatedly Arranging on Monolayer Nanosheets for Efficient and Stable Water‐to‐Hydrogen Conversion. Issue 13 (9th March 2021)

• Record Type: Journal Article
• Authors: Zhang, Qi; Liu, Bingqiu; Li, Lu; Ji, Yue; Wang, Chungang; Zhang, Lingyu; Su, Zhongmin
• Is Part Of: Small. Volume 17:Issue 13(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-03-09
• Subjects: hydrogen evolution reaction -- maximized Schottky effect -- monolayer nanosheets -- ultrafine V 2O 3/Ni heterojunctions -- urea oxidation reaction; Nanotechnology -- Periodicals; Nanoparticles -- Periodicals; Microtechnology -- Periodicals; 620.5
• DOI: 10.1002/smll.202005769
• Languages: English
• ISSNs: 1613-6810

Abstract

Abstract: The Mott–Schottky heterojunction formed at the interface of ultrafine metallic Ni and semiconducting V2 O3 nanoparticles is constructed, and the heterojunctions are "knitted" into the tulle‐like monolayer nanosheets on nickel foam (NF). The greatly reduced particle sizes of both Ni and V2 O3 on the Mott–Schottky heterojunction highly enhance the number of Schottky heterojunctions per unit area of the materials. Moreover, arranging the heterojunctions into the monolayer nanosheets makes the heterojunctions repeat and expose to the electrolyte sufficiently. The Schottky heterojunctions are like countless self‐powered charge transfer workstations embedded in the tulle‐like monolayer nanosheets, promoting maximum of the materials to participate into the electron transfer and become catalytic active sites. In addition, the tulle‐like monolayer nanosheet structure can assist in pumping liquid phase electrolyte to the surface of catalysts, owing to the capillary force. The V2 O3 /Ni/NF Mott–Schottky catalyst exhibits excellent hydrogen evolution reaction (HER) performance with a low η10 of 54 mV and needs −107 mV to get the current density of −100 mA cm −2 . Furthermore, V2 O3 /Ni/NF Schottky electrocatalyst exhibits excellent urea oxidation reaction activity: 1.40, 1.51, and 1.61 V versus reversible hydrogen electrode (RHE) voltage are required to reach a current density of 100, 500, and 1000 mA cm −2, respectively. Abstract : A monolayer nanosheet woven with ultrafine V2 O3 /Ni heterojunctions is prepared. Importantly, with the decrease of the size of nanocrystals at both ends of the heterojunction, the number of heterojunctions on the nanosheet per are increased significantly. The heterojunctions repeatedly arranging on monolayer nanosheets are highly conducive to the exposure of active sites, leading to a great improvement in electrocatalytic performance.