The reactivity of an inorganic glass melt with ZIF-8. Issue 10 (18th February 2021)

• Record Type: Journal Article
• Authors: Longley, Louis; Calahoo, Courtney; Southern, Thomas J. F.; Evans, Rachel C.; Wondraczek, Lothar; Bennett, Thomas D.
• Is Part Of: Dalton transactions. Volume 50:Issue 10(2021)
• Page Start: 3529
• Page End: 3535
• Publication Date: 2021-02-18
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d1dt00152c
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : We characterise mixtures of ZIF-8 and sodium fluoroaluminophosphate glass, this provides a framework for evaluating crystalline MOF inorganic glass pairings. Abstract : The thermal behaviour of ZIF-8, Zn(meIm)2 in the presence of a sodium fluoroaluminophosphate glass melt was probed through differential scanning calorimetry and thermogravimetric analysis. The structural integrity of ZIF-8 was then determined by a combination of powder X-ray diffraction, Fourier transform infra-red and 1 H nuclear magnetic resonance spectroscopy.