Applications of MXene (Ti3C2Tx) in photocatalysis: a review. Issue 5 (18th February 2021)

• Record Type: Journal Article
• Authors: Li, Xing; Bai, Yang; Shi, Xian; Su, Na; Nie, Gongzhe; Zhang, Rumeng; Nie, Hongbo; Ye, Liqun
• Is Part Of: Materials advances. Volume 2:Issue 5(2021)
• Page Start: 1570
• Page End: 1594
• Publication Date: 2021-02-18
• Subjects: 620.11
• DOI: 10.1039/d0ma00938e
• Languages: English
• ISSNs: 2633-5409

Abstract

Abstract : MXenes are two-dimensional nanomaterials, which can be constructed from different elements. Abstract : MXenes are two-dimensional nanomaterials, which can be constructed from different elements. The rich interlayer groups, surface groups, and the flexible layer spacing of MXenes make them ideal catalysts. Among these, Ti3 C2 T x has gained particular attention as a photocatalyst for photocatalytic CO2 reduction reactions (CO2 RR), hydrogen evolution reactions (HER), and photocatalytic degradation reactions. The structure of Ti3 C2 T x, hydrophilic surface functional groups, and the Gibbs free energy for hydrogen adsorption lead to the excellent photocatalytic HER performance of this material. Numerous surface defects on Ti3 C2 T x also provide plentiful CO2 adsorption sites for CO2 RR. It is the structure of two-dimensional nanomaterials and their high-speed electron transport channels that enable their excellent catalytic oxidation activity. However, at present, there are still challenges that limit their further application, the most significant of which is the material stability. In order to overcome this, the synthetic routes to prepare these photocatalysts need to be adapted.